Effects of Ga and Sn on the electrochemical behavior of Mg–6Al–1Zn as anode materials

The microstructure and electrochemical behavior of Mg–6Al–1Zn, Mg–6Al–1Zn–1Ga, Mg–6Al–1Zn–1Sn, and Mg–6Al–1Zn–0.5Sn–0.5Ga as anode materials in a 3.5 wt% NaCl solution are compared systematically. The results show that Sn alloying refines the second-phases of Mg–6Zn–1Al by promoting tiny granular Mg₁₇Al₁₂ phases containing Sn, and inspires their disperse distribution. However, the Ga results in the formation of semicontinuous reticular Ga containing Mg₁₇Al₁₂ phases. The comparison of discharge tests indicates that Mg–6Al–1Zn–1Sn has the highest discharge activity, and Mg–6Al–1Zn–1Ga displays the largest hydrogen evolution corrosion resistance in 3.5 wt% NaCl solution at 298 K. The synergy of Ga and Sn can shorten discharge activation time and promote low discharge potential. In addition, the utilization efficiencies of the alloys decrease as follows: Mg–6Al–1Zn–1Ga > Mg–6Al–1Zn–0.5Sn–0.5Ga > Mg–6Al–1Zn–1Sn > Mg–6Zn–1Al. This study illustrates that the Mg–6Al–1Zn–0.5Sn–0.5Ga alloy has acceptable utilization efficiency and desirable electrochemical activity, which implies that doping Ga and Sn obtains a balance between discharge activity and utilization efficiencies.     

新能源大规模接入背景下的电网企业规划能力综合评价

当前,我国新能源电力飞速发展,新能源大规模的接入给电网企业规划带来了更大的挑战。电网规划研究对象多集中于电网本身,对电网企业规划研究较少。文章在该背景下构建电网企业规划能力评价指标体系,并在组合赋权的基础上建立改进物元可拓模型对实际算例展开电网企业规划能力综合评价。最终验证所提出的模型能在实际应用中有较强的推广性,能帮助电网企业更好地识别自身规划能力。     

全面采矿法在小矿体开采中的应用

介绍了黄背场铅锌矿采用全面采矿法在小矿体开采和探矿中的应用实践,该工艺具有投入少、生产成本低,简单易行等特点,有很强的适应性和实用性。     

智能光电选矿预选抛废技术研究及应用

随着国家对矿产资源开采的不断深入,富矿石、易选矿石逐渐枯竭,入选的贫矿石和难选矿石比例不断上升,导致生产处理成本增加。人工智能、智能光电选矿技术,可以甄别和分拣矿石,实现提前抛废,对矿石进行预富集,提高矿石的入选品位,提升矿石综合利用率,成为解决经济增长中矿产资源短缺重要手段,确保矿产资源安全和矿业经济稳定发展的研究方向。     

Glycine-assisted preparation of highly dispersed Ni/SiO2 catalyst for low-temperature dry reforming of methane

Ni-based catalysts have been widely studied in reforming methane with carbon dioxide. However, Ni-based catalysts tends to form carbon deposition at low temperatures (≤600 °C), compared with high temperatures. In this paper, a series of Ni/SiO₂-XG catalysts were prepared by the glycine-assisted incipient wetness impregnation method, in which X means the molar ratio of glycine to nitrate. XRD, H₂-TPR, TEM and XPS results confirmed that the addition of glycine can increase Ni dispersion and enhance the metal-support interaction. When X ≥ 0.3, these catalysts have strong metal-support interaction and small Ni particle size. The Ni/SiO₂-0.7G catalyst has the best catalytic performance in dry reforming of methane (DRM) test at 600 °C, and its CH₄ conversion is 3.7 times that of Ni/SiO₂-0G catalyst. After 20 h reaction under high GHSV (6 × 10⁵ ml/g_cat/h), the carbon deposition of Ni/SiO₂-0.7G catalyst is obviously lower than that of Ni/SiO₂-0G catalyst. Glycine-assisted impregnation method can enhance the metal-support interaction and decrease the metal particle size，which is a method to prepare highly dispersed and stable Ni-based catalyst.     

Relationship between adjustment of low water level and utilization of water depth in Shashi Reach in middle Yangtze River

Hydrological, sediment, and bathymetric data of the Shashi Reach in the middle Yangtze River for the period of 1975–2018 were collected, and the characteristics of low water level changes and their impacts on utilization of water depth for navigation were investigated. The results showed that, during the study period, the Shashi Reach riverbed was significantly scoured and incised, with cross-sectional profiles showing overall narrowing and deepening. This indicated a strong potential to improve the water depth of the channel. The analysis of the temporal variation of in-channel topographical features showed that the Taipingkou diara underwent siltation and erosion, with its head gradually scoured and relocated downstream after 2008, and the Sanbatan diara continued to shrink and migrate leftwards. Low water levels with the same flow rate over the study period decreased. For instance, from 2003 to 2020, the water level at the Shashi hydrological station decreased to 1.37 m with a flow rate of 6 000 m³/s. Furthermore, the designed minimum navigable water level of the Shashi Reach was approximately 2.11 m lower than the recommended level. In terms of utilization of the channel water depth, continuous scouring of the river channel is expected to result in a reduction in discharge at the Taipingkou mouth, which will improve the water depth conditions of the channel during the dry season in the Shashi Reach. With several channel regulation projects, the 3.5-m depth of the Shashi Reach would basically be unobstructed. This promotes utilization of the shipping route from the Taipingkou south branch to the Sanbatan north branch as the main navigation channel during the dry season. Considering the factors of current water depth and the clear width limitation of the navigation hole at the Jingzhou Yangtze River Bridge, this route can still be favored as the main navigation channel with a 4.5-m depth during the dry season.     

隧洞开挖典型掏槽设计方法

针对目前隧洞开挖爆破施工中缺少具体、详细的掏槽设计方法的现状,提出了最常用的2种典型掏槽方式,并详细论述了其设计方法。这些掏槽方式及设计方法均在实际施工中得到了推广应用,并且取得了良好的爆破效果。实际应用表明:这些典型掏槽方式及设计方法能有效提高硬质岩石开挖的钻孔利用率,能将钻孔利用率提高到98%～100%,实现掌子面基本无残孔,从而有效提高单循环进尺,加快开挖进度,降低开挖成本。